Boiler Hydro Test - Free download as PDF File (.pdf), Text File (.txt) or read online for free. Figure 3-14. In cooling water systems, silica forms deposits when solubility limits are exceeded. Reactive silica is the form of silica to be used in RO projection programs. PROBLEM TO BE SOLVED: To provide a silica concentration control method in boiler water capable of automatically controlling silica concentration in boiler water upon a boiler being started and upon ordinary operation. 2. Under certain conditions, silica forms troublesome silica and silicate scales, particularly on high-pressure steam turbine blades. The process of water treatment in boilers is not limited to producing high quality DM water. Silica content of the boiler water is critical for steam turbines and scaling of boiler heat transfer surfaces. 2.1 Water-Tube Boilers ( Drum Type) - The feed water, boiler water and condensate, for water-tube boilers shall cotiply with the requirements given in Table 1. A boiler that makes up 4000 gal/day of water having 100 ppm of hardness, has a potential of accumulating over 1000 pounds of scale per year. Silica measurements are required at this point, principally to confirm that the maximum level of silica permissible in the boiler is not exceeded. High boiler water silica content can result in silica vaporization with the steam, and, under certain circumstances, siliceous scale. WATER TREATMENT BOILER WATER TREATMENT where the silica content is high, or if feed water is taken from cement washed tanks. Taylor’s Boiler & Cooling Water Test Kits INTRODUCTION. silicate, various forms of iron oxide, silica adsorbed on the previously mentioned precipitates, and alumina (see Table 39.1). analyze both the natural impurities of the source water and the treated water’s characteristics. This can be written as: Example 3.12.3. Silica content of the boiler water is critical for steam turbines and scaling of boiler heat transfer surfaces. Silica DOC316.53.01132 Heteropoly Blue Method1 Method 8186 0.010 to 1.600 mg/L SiO2 (spectrophotometers) 0.01 to 1.60 mg/L SiO2 (colorimeters) Powder Pillows Scope and application: For boiler and ultrapure water. For most dissolved solids found in boiler water, it is negligible by comparison to mechanical carryover at pressures less than 2000 psig (13.8 MPa). Test preparation It is not affected by boiler design. To give warning on acidity or alkalinity of boiler water sample. Steam contamination (solid particles in the superheated steam) comes from the boiler water largely in the carry‐over of water droplets. Chem. Accordingly, a test for hardness in the. You must maintain a Total OH alkalinity ratio of 3:1 in high pressure boilers to prevent plating of silica. Anal. When treating boiler feed water (the combination of boiler makeup and condensate return water), several issues can arise that cause boiler scaling, corrosion, fouling, and system failure.. Below, we break down the most common boiler feed water issues and how to avoid them to help ensure system efficiency and operational safety. When sodium zeolite softened makeup is used, the need for boiler blowdown is usually determined by measurement of the boiler water conductivity, which provides an indirect measure of the boiler water dissolved solids. Silica (sio2) is an oxide of silicon, and is present in almost all minerals. In certain cases, when row water is evaporated and is high in silica, carry-over may admit silica into the distilled water system. Consequently, steam contamination has been steadily reduced. Typical tests used for boiler feedwater include: Chloride or salinity Conductivity Dissolved Oxygen Hardness Iron and Manganese pH Silica Sulphite Suspended Solids Water Treatment of Silica. Vaporous carryover depends on pressure and on boiler water chemistry. Another important source of silica in water is the sand watertreatments filter.When water treated by lime-soda process is filtered through a sand water filter, a good amount of silica dissolves in it (forming calcium and magnesium silicates) due to alkaline nature of waters. 1 Adapted from Standard Methods for the Examination of Water and Wastewater. The standard test for the analysis of silica in water is a rapid technique based upon the blue reduced silicomolybdate complex. Scale creates a problem because it typically possesses a thermal conductivity less … 5.1 Control of silica in boiler feedwater and boiler water is necessary to minimize the formation of scale-forming silicates that decrease heat transfer in the boiler. Silica Levels Allowed in Boiler Water. On some new vessels Ed. Why does steam carry silica and where does it come from if FEED WATER SILICA is zero? Ind. Acmite (Sodium Ferrous Silica - Na 2 Fe 2 O 3 4SiO 2) and crust Fe - Si can be formed from corrosion result. For boiler water, the conductivity increases at the rate of approximately 2% (of the value at 25°C) for every 1°C increase in temperature. A boiler water sample has an unneutralised conductivity of 5 000 μS/cm at 25°C. OR SEARCH CITATIONS Alkalinity Test In natural waters, alkalinity is most commonly the result of bicarbonate and carbonate ions; in treated waters, alkalinity may also be contributed by hydroxide, phosphate, silicate, and other treatment ions. An exception is silica for which vaporous carryover can be substantial at lower pressures. Silica is reaching out of control in super heated steam having value 3.2 to 4.0 PPM, but boiler feed water parameter is TDS-2, pH-8.6, P.Alkalinity-01, M.Alkalinity-02, Total hardness-00 and SILICA IS 00 PPM. An increase in temperature results in an increase in electrical conductivity. The silica concentration is distributed between the water and vapour phases in a boiler… PH Value (Reciprocal or Hydrogen Ion) Test 7.5 – 14.0 for Boiler Water 6.5 – 10.0 for Condensate Water Purpose: 1. If phosphate salts are used to treat the boiler water, calcium will preferentially precipitate as the phosphate before pre-cipitating as the carbonate, and … Alkalinity is a measure of the capacity of water to neutralize strong acids. Boiler feedwater is usually a combination of returned condensate plus pre-treated makeup water from a softener, reverse osmosis, or other purification system. Manual on Boiler Hydro Test Feed-water purity requirements therefore can vary widely. Eng. Unlike Carbonate and Sulphate ions, the Chloride ion does not precipitate in the presence of soluble Calcium. 9 – Boiler Drum Silica build-up is monitored inside the boiler drum. A low-pressure fire-tube boiler can usually tolerate high feed-water hardness with proper treatment while virtually all impurities must be removed from water used in some modern, high-pressure boilers. The measured silica concentration is compared with reference silica … T. o prevent corrosion and scale in boiler and cooling water . SOLUTION: Pressure of boiler water and silica concentration at that time are actually measured. This necessitates the use of a high quality water treatment system. Boiler water quality is of prime concern to all boiler operators. Model PBC-DT Professional Boiler Treatment/Boiler Feed and Cooling Water Test… Hach In addition to all of the test offered in Model BT-DT (2350600) this test kit provides testing capability for iron, silica, chlorine, nitrite, and total dissolved solids (TDS). ¾TIP 0416-03– Water Quality and Monitoring Requirements for Paper Mill Boilers Operating on High Purity Water, 1999 ¾TIP 0416-04– Design Engineer Decision Tree: Paper Mill Boiler Feedwater, 1999 ¾TIP 0416-05– Response to Contamination of High Purity Boiler Feedwater, 2000 ¾TIP 0416-06– Keys to Successful Chemical Cleaning of systems, it is essential to . The three common kinds of silica are soluble, colloidal and particulate. Silica – this may be the blowdown controlling factor in softened waters containing high silica. Little aluminum content in feedwater can cause high deposit of silica in boiler water. It is found in surface and well water. The stringent water chemistry requirements of Supercritical power plants makes water treatment in boilers a very critical aspect of power plant operation. 5.3 Silica concentration is an important consideration in some industrial installations such as steam generation and cooling water systems. the pH of the boiler water will decrease until acid conditions result in corrosion of the metal surfaces. Silica Test Kit. If an economical blowdown rate is to be maintained, suitable boiler water tests must be run frequently to check concentrations in the boiler water. Silica Photometer & Comparator Tablet Reagents - AP181 for use when testing Silica in boiler water Silica in boiler feedwater can be a problem in larger steam boiler systems. Scale deposits occur when calcium, magnesium, and silica, commonly found in water supplies, react to form a continuous layer of material on the waterside of the boiler heat exchange tubes. Silica (SiO 2) Silica scale is not normally found in boiler systems except in minute quantities. All Publications/Website. condensate must also be performed. Natural waters, generally, contain about 5-8 mg/l of silica (Si0,). Silica content of the boiler water is not as … The need for extreme purity of steam for use in high pressure turbines has prompted the development of highly satisfactory devices for separating steam and water in a boiler drum. Silica is a problem for high pressure boilers, as it exhibits enough volatility that high pressure boilers will have silica carry over to the vapour partition. chirag singh - ambala, haryana,india Therefore feedwater treatment must be controlled to eliminate aluminum and silica. Volatilization and carryover of silica with the steam may cause hard, glassy siliceous deposits to form on turbine blades that reduce turbine efficiency. 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